Main.cf

The default file has many helpful comments, so try to avoid simply replacing the whole file with these:

queue_directory = /var/spool/postfix
command_directory = /usr/sbin
daemon_directory = /usr/libexec/postfix
mail_owner = postfix
myorigin = physics.$mydomain
inet_interfaces = $myhostname, localhost
mydestination = $myhostname, localhost.$mydomain, localhost, $mydomain,
                hash:/etc/postfix/domains
unknown_local_recipient_reject_code = 550
relay_domains =
alias_maps = hash:/etc/aliases
alias_database = hash:/etc/aliases
debug_peer_level = 2
debugger_command =
         PATH=/bin:/usr/bin:/usr/local/bin:/usr/X11R6/bin
         xxgdb $daemon_directory/$process_name $process_id & sleep 5
sendmail_path = /usr/sbin/sendmail.postfix
newaliases_path = /usr/bin/newaliases.postfix
mailq_path = /usr/bin/mailq.postfix
setgid_group = postdrop
html_directory = no
manpage_directory = /usr/share/man
sample_directory = /usr/share/doc/postfix-2.3.3/samples
readme_directory = /usr/share/doc/postfix-2.3.3/README_FILES

etc/postfix/domains contains some names:

nuclear.unh.edu                  OK
physics.unh.edu                  OK
werner-heisenberg.unh.edu        OK
www.theory.unh.edu               OK
xenon.unh.edu                    OK